Aromatic Monochlorination Photosensitized by DDQ with Hydrogen Chloride under Visible‐Light Irradiation
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چکیده
منابع مشابه
Metal-free oxygenation of cyclohexane with oxygen catalyzed by 9-mesityl-10-methylacridinium and hydrogen chloride under visible light irradiation.
Photooxygenation of cyclohexane by O(2) occurs efficiently under visible-light irradiation of an O(2)-saturated acetonitrile solution containing 9-mesityl-10-methylacridinium ions (Acr(+)-Mes) and HCl to yield cyclohexanone, cyclohexanol and hydrogen peroxide. The photocatalytic reaction is initiated by electron transfer from Cl(-) to the mesitylene radical cation moiety.
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ژورنال
عنوان ژورنال: Chemistry – An Asian Journal
سال: 2016
ISSN: 1861-4728,1861-471X
DOI: 10.1002/asia.201600083